Structural and photophysical properties of a mononuclear Re(I) complex: [P,N-{(C6H5)2(C5H 5N)P}Re(CO)3Br]

Felipe Venegas, Nancy Pizarro, Andres Vega

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21 Citations (Scopus)

Abstract

We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2 (C5H 5N)P}Re(CO) 3Br] by direct reaction of (Re(CO) 3Br(THF)) 2 and the ligand (C6H 5)2 (C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.

Original languageEnglish
Pages (from-to)823-826
Number of pages4
JournalJournal of the Chilean Chemical Society
Volume56
Issue number3
DOIs
Publication statusPublished - 2011

ASJC Scopus subject areas

  • Chemistry(all)

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