Structural and electronic properties of Polyoxovanadoborates containing the [V                         
                        12
                                                 B                         
                        18
                                                 O                         
                        60
                                                 ] core in different mixed valence states

Patricio Hermosilla-Ibáñez; Karina Muñoz-Becerra; Verónica Paredes-García; Eric Le Fur; Evgenia Spodine; Diego Venegas-Yazigi

doi:10.3390/inorganics3030309

Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states

Patricio Hermosilla-Ibáñez, Karina Muñoz-Becerra, Verónica Paredes-García, Eric Le Fur, Evgenia Spodine, Diego Venegas-Yazigi

Research output: Contribution to journal › Review article › peer-review

9 Citations (Scopus)

Abstract

This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V ₁₂ B ₁₈ O ₆₀ ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.

Original language	English
Pages (from-to)	309-331
Number of pages	23
Journal	Inorganics
Volume	3
Issue number	3
DOIs	https://doi.org/10.3390/inorganics3030309
Publication status	Published - 1 Sept 2015

Keywords

Electronic properties
FT-IR
Magnetic behavior
Polyoxovanadoborate
Reflectance UV-vis
VBO
[V B O ]

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.3390/inorganics3030309

Cite this

Hermosilla-Ibáñez, P., Muñoz-Becerra, K., Paredes-García, V., Fur, E. L., Spodine, E., & Venegas-Yazigi, D. (2015). Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states. Inorganics, 3(3), 309-331. https://doi.org/10.3390/inorganics3030309

Hermosilla-Ibáñez, Patricio ; Muñoz-Becerra, Karina ; Paredes-García, Verónica et al. / Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states. In: Inorganics. 2015 ; Vol. 3, No. 3. pp. 309-331.

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title = "Structural and electronic properties of Polyoxovanadoborates containing the [V 12 B 18 O 60 ] core in different mixed valence states",

abstract = " This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.",

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author = "Patricio Hermosilla-Ib{\'a}{\~n}ez and Karina Mu{\~n}oz-Becerra and Ver{\'o}nica Paredes-Garc{\'i}a and Fur, {Eric Le} and Evgenia Spodine and Diego Venegas-Yazigi",

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Hermosilla-Ibáñez, P, Muñoz-Becerra, K, Paredes-García, V, Fur, EL, Spodine, E & Venegas-Yazigi, D 2015, 'Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states', Inorganics, vol. 3, no. 3, pp. 309-331. https://doi.org/10.3390/inorganics3030309

Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states. / Hermosilla-Ibáñez, Patricio; Muñoz-Becerra, Karina; Paredes-García, Verónica et al.
In: Inorganics, Vol. 3, No. 3, 01.09.2015, p. 309-331.

Research output: Contribution to journal › Review article › peer-review

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AU - Hermosilla-Ibáñez, Patricio

AU - Muñoz-Becerra, Karina

AU - Paredes-García, Verónica

AU - Fur, Eric Le

AU - Spodine, Evgenia

AU - Venegas-Yazigi, Diego

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AB - This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V 12 B 18 O 60 ] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations such as protonated amines, hydronium, and alkaline, and transition metal ions. The cluster is shown to form extended 1D, 2D, or 3D frameworks by forming covalent bonds or presenting hydrogen bond interactions with the present secondary cations. These cations have little influence on the solid state reflectance UV-visible spectra of the polyanionic cluster, but are shown to modify the FT-IR spectra and the magnetic behavior of the different reported species.

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Hermosilla-Ibáñez P, Muñoz-Becerra K, Paredes-García V, Fur EL, Spodine E, Venegas-Yazigi D. Structural and electronic properties of Polyoxovanadoborates containing the [V ₁₂ B ₁₈ O ₆₀ ] core in different mixed valence states. Inorganics. 2015 Sept 1;3(3):309-331. doi: 10.3390/inorganics3030309