Steric control in the synthesis of trans-(1α-H; 5β-OH)-3,10-guaiadien-6,12-Olide

Victor Kesternich, Rolando Martinez

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Abstract

The first biomimetic synthesis of trans-(1α-H;5β-OH)-3,10-guaiadien-6,12-olide was possible via allylic induction over the epoxidation as key step. The starting material was α-santonin, an eudesmanolide.

Original languageEnglish
Pages (from-to)401-403
Number of pages3
JournalBoletin de la Sociedad Chilena de Quimica
Volume42
Issue number3
Publication statusPublished - 1997

ASJC Scopus subject areas

  • Chemistry(all)

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