Abstract
Dirac molecular spinor calculations on the Re2Cl 8 2-, Re2Br8 2-, Os 2Cl8 2- (both staggered and eclipsed isomers), Os2Br8 2- and Os2I8 2- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the π and δ metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.
Original language | English |
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Pages (from-to) | 361-365 |
Number of pages | 5 |
Journal | Journal of the Chilean Chemical Society |
Volume | 49 |
Issue number | 4 |
Publication status | Published - Dec 2004 |
ASJC Scopus subject areas
- General Chemistry