Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

P. Hermosilla-Ibáñez; J. Costamagna; A. Vega; V. Paredes-García; M. T. Garland; E. Le Fur; E. Spodine; D. Venegas-Yazigi

doi:10.1134/S0022476614080125

Protonated diamines as linkers in the supramolecular assemblies based on the [V₁₂B₁₈O₆₀H₆] polyoxovanadoborate anion

P. Hermosilla-Ibáñez, J. Costamagna, A. Vega, V. Paredes-García, M. T. Garland, E. Le Fur, E. Spodine, D. Venegas-Yazigi

Exact Sciences School

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Two new polyoxovanadoborates based crystalline lattices are being reported: K₅(H₃O)₂(1,3-diapH₂)₂[V₁₂B₁₈O₆₀H₆]·10.80H₂O (1), and K₂(H₃O)₇(enH₂)[V₁₂B₁₈O₆₀H₆]·9H₂O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH₂ and 1,3-diapH₂) and hydronium ions, and the oxygen atoms of the [V₁₂B₁₈O₆₀H₆] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V₁₂B₁₈O₆₀H₆] anionic cluster for (1) and (2) being 11/1 (V^IV/V^V) ratio.

Original language	English
Pages (from-to)	1453-1465
Number of pages	13
Journal	Journal of Structural Chemistry
Volume	55
Issue number	8
DOIs	https://doi.org/10.1134/S0022476614080125
Publication status	Published - Dec 2014

Keywords

BVO
mixed valence
polyoxometalate
polyoxovanadate
supramolecular

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1134/S0022476614080125

Cite this

@article{dbab1c07b124465ca06705bbf57edefa,

title = "Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion",

abstract = "Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.",

keywords = "BVO, mixed valence, polyoxometalate, polyoxovanadate, supramolecular",

author = "P. Hermosilla-Ib{\'a}{\~n}ez and J. Costamagna and A. Vega and V. Paredes-Garc{\'i}a and Garland, {M. T.} and {Le Fur}, E. and E. Spodine and D. Venegas-Yazigi",

note = "Funding Information: Authors acknowledge FONDECYT 1120004 and Financiamiento Basal Program FB0807 for partial financial support. This work was done under the LIA-MIF CNRS 836 Collaborative Program. PHI thanks MECESUP UCH 0601 Doctoral Scholarship. PHI also thanks CONICYT AT-24100222 and TT-23120099 Doctoral Scholarships. Thanks are given to the Consejo Superior de Investigaciones Cient{\'i}ficas (CSIC) of Spain for the award of a license for the use of the Cambridge Crystallographic Data Base (CSD).",

year = "2014",

month = dec,

doi = "10.1134/S0022476614080125",

language = "English",

volume = "55",

pages = "1453--1465",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "8",

}

TY - JOUR

T1 - Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

AU - Hermosilla-Ibáñez, P.

AU - Costamagna, J.

AU - Vega, A.

AU - Paredes-García, V.

AU - Garland, M. T.

AU - Le Fur, E.

AU - Spodine, E.

AU - Venegas-Yazigi, D.

N1 - Funding Information: Authors acknowledge FONDECYT 1120004 and Financiamiento Basal Program FB0807 for partial financial support. This work was done under the LIA-MIF CNRS 836 Collaborative Program. PHI thanks MECESUP UCH 0601 Doctoral Scholarship. PHI also thanks CONICYT AT-24100222 and TT-23120099 Doctoral Scholarships. Thanks are given to the Consejo Superior de Investigaciones Científicas (CSIC) of Spain for the award of a license for the use of the Cambridge Crystallographic Data Base (CSD).

PY - 2014/12

Y1 - 2014/12

N2 - Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

AB - Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

KW - BVO

KW - mixed valence

KW - polyoxometalate

KW - polyoxovanadate

KW - supramolecular

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U2 - 10.1134/S0022476614080125

DO - 10.1134/S0022476614080125

M3 - Article

AN - SCOPUS:84921713126

SN - 0022-4766

VL - 55

SP - 1453

EP - 1465

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 8

ER -