Nonacarbonyl-μ2-hydrido-μ 2-(N-methylcarboxamido)-C:O-(N-trimethylamine)triosmium(3 Os - Os)

Andrés Vega, Evgenia Spodine, Alejandro Arce, Jorge Manzur, Ana María García, María Teresa Garland

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)


In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.

Original languageEnglish
Pages (from-to)322-323
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Issue number3
Publication statusPublished - 15 Mar 1999

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)


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