In the title compound, nonacarbonyl-1κ2C,2κ3C,3κ 4C-μ-hydrido-1:2κ 2H-μ-(N-methylcarboxamido)-1:2κ 2O:C-(N-trimethylamine-1κN)triosmium(3 Os-Os), [Os3H-(C2H4NO)(C3H 9N)(CO)9], the MeHNCO ligand forms a μ2-C:O bridge between two metal centers, which are also linked by a μ-hydride ligand. These two groups are at opposite sides of the plane defined by the Os atoms. Bond lengths between Os atoms are 2.8149 (8), 2.8777 (8) and 2.9278 (8) Å. The structure shows two metal centers which are heptacoordinated and one which is hexacoordinated.
|Number of pages||2|
|Journal||Acta Crystallographica Section C: Crystal Structure Communications|
|Publication status||Published - 15 Mar 1999|
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)