Noble metal nanoparticles supported on titanate nanotubes as catalysts for selective hydrogenation of nitroarenes

Krishnamoorthy Shanmugaraj, Tatiana M. Bustamante, J. N.Díaz de León, Radhamanohar Aepuru, Ramalinga Viswanathan Mangalaraja, Cecilia C. Torres, Cristian H. Campos

Research output: Contribution to journalArticlepeer-review

Abstract

Platinum (Pt) and palladium (Pd) nanoparticles (NPs) supported on titanate nanotubes (TiNTs) [email protected] and [email protected] were prepared for the liquid-phase hydrogenation of nitroarenes at 25 °C Initially, TiNT was modified with 3-aminopropyl-trimethoxysilane to provide a strong anchoring site to trap the Pt and Pd NPs, which prevent the metal NPs from leaching. As-prepared 1 wt% of metal loading catalysts were characterized by transmission electron microscopy (TEM), nitrogen adsorption–desorption isotherms, X-ray diffraction, and X-ray photoelectron spectroscopy measurements. The TEM images confirmed that the Pt (1.70 ± 0.19 nm) and Pd (2.80 ± 0.43 nm) NPs were mainly confined into the channel of TiNTs. Both catalysts exhibited excellent catalytic performances for the reduction of nitrobenzene as a model compound under mild reaction conditions. The superior catalytic activity for the hydrogenation of nitroarenes is attributed to the small size of the Pt and Pd NPs. However, the operational stability showed that [email protected] retained its catalytic performance after 10 cycles, while [email protected] suffered deactivation by metal sintering after the sixth cycle. The [email protected] system exhibited high efficiency in the hydrogenation of different substituted nitroarenes of pharmaceuticals interest, and it showed an excellent activity and selectivity toward the production of desired substituted anilines.

Original languageEnglish
JournalCatalysis Today
DOIs
Publication statusAccepted/In press - 2021

Keywords

  • Confinement effect
  • Hydrogenation
  • Nitroarenes
  • Noble metals nanoparticles
  • Titanate nanotubes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Noble metal nanoparticles supported on titanate nanotubes as catalysts for selective hydrogenation of nitroarenes'. Together they form a unique fingerprint.

Cite this