Ni2[LnCl6] (Ln = EuII, CeII, GdII): The first LnII compounds stabilized in a pure inorganic lattice

Bianca Baldo, Francisco Rubio, Erwin Flores, Andres Vega, Nathalie Audebrand, Diego Venegas-Yazigi, Verónica Paredes-García

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Abstract

Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.

Original languageEnglish
Pages (from-to)7531-7534
Number of pages4
JournalChemical Communications
Volume54
Issue number54
DOIs
Publication statusPublished - 1 Jan 2018

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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