TY - JOUR
T1 - Ni2[LnCl6] (Ln = EuII, CeII, GdII)
T2 - The first LnII compounds stabilized in a pure inorganic lattice
AU - Baldo, Bianca
AU - Rubio, Francisco
AU - Flores, Erwin
AU - Vega, Andres
AU - Audebrand, Nathalie
AU - Venegas-Yazigi, Diego
AU - Paredes-García, Verónica
N1 - Funding Information:
The authors acknowledge FONDECYT 1170887, Proyecto Anillo CONICYT ACT 1404 grant, CONICYT-FONDEQUIP/PPMS/ EQM130086, Chilean-French International Associated Laboratory for Multifunctional Molecules and Materials-LIAM3-CNRS No. 1027 and ECOS/CONICYT C15E02. The authors acknowledge CEDENNA, Financiamiento Basal, FB0807. The authors also acknowledge the support from the Laboratory of Analyses of Solids (L.A.S-UNAB). B. B. thanks CONICYT scholarship No. 21140908.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.
AB - Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.
UR - http://www.scopus.com/inward/record.url?scp=85049504703&partnerID=8YFLogxK
U2 - 10.1039/c7cc09921e
DO - 10.1039/c7cc09921e
M3 - Article
AN - SCOPUS:85049504703
SN - 1359-7345
VL - 54
SP - 7531
EP - 7534
JO - Chemical Communications
JF - Chemical Communications
IS - 54
ER -