First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

Pablo Fuentealba; Catalina Cortés; Nathalie Audebrand; Eric Le Fur; Verónica Paredes-García; Diego Venegas-Yazigi; Jorge Manzur; Evgenia Spodine

doi:10.1039/c5dt01540e

First copper(ii) phase M′_0.2Mn_0.8PS₃·0.25H₂O and analogous M′ = Co^II, Ni^II and Zn^II materials obtained by microwave assisted synthesis

Pablo Fuentealba, Catalina Cortés, Nathalie Audebrand, Eric Le Fur, Verónica Paredes-García, Diego Venegas-Yazigi, Jorge Manzur, Evgenia Spodine

Exact Sciences School

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

M′_0.2Mn_0.8PS₃·0.25H₂O materials are obtained by a mild microwave assisted reaction (M′ = Co^II, Ni^II, Cu^II, Zn^II), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS₃.

Original language	English
Pages (from-to)	12493-12496
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	28
DOIs	https://doi.org/10.1039/c5dt01540e
Publication status	Published - 28 Jul 2015

ASJC Scopus subject areas

Inorganic Chemistry

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title = "First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis",

abstract = "M′0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.",

author = "Pablo Fuentealba and Catalina Cort{\'e}s and Nathalie Audebrand and {Le Fur}, Eric and Ver{\'o}nica Paredes-Garc{\'i}a and Diego Venegas-Yazigi and Jorge Manzur and Evgenia Spodine",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

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T1 - First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

AU - Fuentealba, Pablo

AU - Cortés, Catalina

AU - Audebrand, Nathalie

AU - Le Fur, Eric

AU - Paredes-García, Verónica

AU - Venegas-Yazigi, Diego

AU - Manzur, Jorge

AU - Spodine, Evgenia

PY - 2015/7/28

Y1 - 2015/7/28

N2 - M′0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.

AB - M′0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.

UR - http://www.scopus.com/inward/record.url?scp=84936861413&partnerID=8YFLogxK

U2 - 10.1039/c5dt01540e

DO - 10.1039/c5dt01540e

M3 - Article

AN - SCOPUS:84936861413

SN - 1477-9226

VL - 44

SP - 12493

EP - 12496

JO - Dalton Transactions

JF - Dalton Transactions

IS - 28

ER -

First copper(ii) phase M′_0.2Mn_0.8PS₃·0.25H₂O and analogous M′ = Co^II, Ni^II and Zn^II materials obtained by microwave assisted synthesis

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