Di-μ-hydroxo-bis{(acetonitrile)di-benzyl(6-methyl-2-pyridylmethyl) amine-κ2N,Ncopper(II)} bis(perchlorate)

Dario Rojas, Ana María García, Jorge Manzur, Andrés Vega

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The title compound corresponds to a copper(II) dimer, [CU 2(OH)2(C2H3N)2(C 21H22N2)2](ClO4) 2, where the metal centres are μ2-bridged by hydroxo groups. The coordination of each copper(II) centre is a slightly distorted square-based pyramid, with two N atoms from dibenzyl(6-methyl-2-pyridylmethyl) amine (BiBzMePMA) and two hydroxo O atoms occupying the basal positions, and the acetonitrile N atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 2.9522 (9) Å]

Original languageEnglish
Pages (from-to)m115-m116
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number2
DOIs
Publication statusPublished - Feb 2005

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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