{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

P. Cancino; V. Paredes-García; J. Torres; S. Martínez; C. Kremer; E. Spodine

doi:10.1039/c7cy01385j

{[Cu₃Lu₂(ODA)₆(H₂O)₆]·10H₂O}_{: N}: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

P. Cancino, V. Paredes-García, J. Torres, S. Martínez, C. Kremer, E. Spodine

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The catalytic performance of the novel framework {[Cu₃Lu₂(ODA)₆(H₂O)₆]·10H₂O}_n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O₂) as oxidants. Excellent conversions were obtained with O₂ under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

Original language	English
Pages (from-to)	4929-4933
Number of pages	5
Journal	Catalysis Science and Technology
Volume	7
Issue number	21
DOIs	https://doi.org/10.1039/c7cy01385j
Publication status	Published - 1 Jan 2017

ASJC Scopus subject areas

Catalysis

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10.1039/c7cy01385j

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title = "{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates",

abstract = "The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).",

author = "P. Cancino and V. Paredes-Garc{\'i}a and J. Torres and S. Mart{\'i}nez and C. Kremer and E. Spodine",

note = "Funding Information: The authors acknowledge Proyecto Anillo ACT 1404 and Basal Funding FB0807 (CEDENNA) for financial support. C. K. thanks CSIC (Uruguay) for financial support through Programa de Apoyo a Grupos de Investigaci{\'o}n.",

year = "2017",

month = jan,

day = "1",

doi = "10.1039/c7cy01385j",

language = "English",

volume = "7",

pages = "4929--4933",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "21",

}

{[Cu₃Lu₂(ODA)₆(H₂O)₆]·10H₂O}_{: N}: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates. / Cancino, P.; Paredes-García, V.; Torres, J. et al.
In: Catalysis Science and Technology, Vol. 7, No. 21, 01.01.2017, p. 4929-4933.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - {[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

AU - Cancino, P.

AU - Paredes-García, V.

AU - Torres, J.

AU - Martínez, S.

AU - Kremer, C.

AU - Spodine, E.

N1 - Funding Information: The authors acknowledge Proyecto Anillo ACT 1404 and Basal Funding FB0807 (CEDENNA) for financial support. C. K. thanks CSIC (Uruguay) for financial support through Programa de Apoyo a Grupos de Investigación.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

AB - The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

UR - http://www.scopus.com/inward/record.url?scp=85032729367&partnerID=8YFLogxK

U2 - 10.1039/c7cy01385j

DO - 10.1039/c7cy01385j

M3 - Article

AN - SCOPUS:85032729367

SN - 2044-4753

VL - 7

SP - 4929

EP - 4933

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 21

ER -

{[Cu₃Lu₂(ODA)₆(H₂O)₆]·10H₂O}_{: N}: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

Abstract

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