{[Cu3Lu2(ODA)6(H2O)6]·10H2O}: N: The first heterometallic framework based on copper(II)/lutetium(III) for the catalytic oxidation of olefins and aromatic benzylic substrates

P. Cancino, V. Paredes-García, J. Torres, S. Martínez, C. Kremer, E. Spodine

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).

Original languageEnglish
Pages (from-to)4929-4933
Number of pages5
JournalCatalysis Science and Technology
Volume7
Issue number21
DOIs
Publication statusPublished - 1 Jan 2017

ASJC Scopus subject areas

  • Catalysis

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