A novel coordination polymer based on decavanadate units linked by copper(II) ethylenediamine complexes

Diego Venegas-Yazigi, Patricio Hermosilla-Ibáñez, Juan Costamagna, Evgenia Spodine, Andrés Vega, Verónica Paredes-García, Eric Le Fur

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A novel coordination polymer[{Cu(en)2}(V10O 28)]n · 2n[Cu(en)2(H2O)] · 2n(H3BO3) · 2n(H2O) was obtained by hydrothermal reaction. The compound crystallizes in the monoclinic crystal system, in the C2/c space group, with a = 26.490 (3) Å; b = 11.6558 (11) Å; c = 19.8426 (19) Å; β = 124.011 (1)°; V = 5078.6(8) Å3. The solid structure is formed by polymeric chains, [Cu(en)2(H2O)]2+ cations, and boric acid and water solvate molecules, stabilized through a multiple hydrogen bond network.

Original languageEnglish
Pages (from-to)80-86
Number of pages7
JournalMacromolecular Symposia
Volume304
Issue number1
DOIs
Publication statusPublished - Jun 2011

Keywords

  • Inorganic polymer
  • copper(II)
  • decavanadate
  • hydrothermal
  • infinite chain

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'A novel coordination polymer based on decavanadate units linked by copper(II) ethylenediamine complexes'. Together they form a unique fingerprint.

Cite this