A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

César Morales-Verdejo; Luciano Oehninger; Iván Martínez-Díaz; Desmond Mac-Leod Carey; Ramiro Arratia-Pérez; Ivonne Chávez; Juan Manuel Manríquez

doi:10.1016/j.ica.2012.08.010

A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

César Morales-Verdejo, Luciano Oehninger, Iván Martínez-Díaz, Desmond Mac-Leod Carey, Ramiro Arratia-Pérez, Ivonne Chávez, Juan Manuel Manríquez

Exact Sciences School

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

This work describes the synthesis and characterization by means of ¹H, ¹³C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)₃Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)₃Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)]₂. Secondly, its respective carbonylated complex [(CO)₃Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)₂] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

Original language	English
Pages (from-to)	132-139
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	394
DOIs	https://doi.org/10.1016/j.ica.2012.08.010
Publication status	Published - 1 Jan 2013

Keywords

DFT
Heterobimetallic complexes
Organometallic

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2012.08.010

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title = "A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene",

abstract = "This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)]2. Secondly, its respective carbonylated complex [(CO)3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.",

keywords = "DFT, Heterobimetallic complexes, Organometallic",

author = "C{\'e}sar Morales-Verdejo and Luciano Oehninger and Iv{\'a}n Mart{\'i}nez-D{\'i}az and {Mac-Leod Carey}, Desmond and Ramiro Arratia-P{\'e}rez and Ivonne Ch{\'a}vez and Manr{\'i}quez, {Juan Manuel}",

note = "Funding Information: The authors are grateful for the financial support of FONDECYT Grant Nos. 11110273 , 1060588 , 1060589 ; 1100283 , 1110758 , 11100027 , Ph.D. Scholarship CONICYT, Apoyo de Tesis Doctoral CONICYT Grant Nos. 23070215 , 24080034 ; UNAB-DI-52-11/R; UNAB-DI-17-11/R; Project Milennium No. P07-006-F; ECO-NET Program No. 18824SD.",

year = "2013",

month = jan,

day = "1",

doi = "10.1016/j.ica.2012.08.010",

language = "English",

volume = "394",

pages = "132--139",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

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TY - JOUR

T1 - A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

AU - Morales-Verdejo, César

AU - Oehninger, Luciano

AU - Martínez-Díaz, Iván

AU - Mac-Leod Carey, Desmond

AU - Arratia-Pérez, Ramiro

AU - Chávez, Ivonne

AU - Manríquez, Juan Manuel

N1 - Funding Information: The authors are grateful for the financial support of FONDECYT Grant Nos. 11110273 , 1060588 , 1060589 ; 1100283 , 1110758 , 11100027 , Ph.D. Scholarship CONICYT, Apoyo de Tesis Doctoral CONICYT Grant Nos. 23070215 , 24080034 ; UNAB-DI-52-11/R; UNAB-DI-17-11/R; Project Milennium No. P07-006-F; ECO-NET Program No. 18824SD.

PY - 2013/1/1

Y1 - 2013/1/1

N2 - This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)]2. Secondly, its respective carbonylated complex [(CO)3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

AB - This work describes the synthesis and characterization by means of 1H, 13C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)3Mn(2,6-diethyl-4,8- dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)3Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(μ-Cl)(COD)]2. Secondly, its respective carbonylated complex [(CO)3Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)2] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.

KW - DFT

KW - Heterobimetallic complexes

KW - Organometallic

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DO - 10.1016/j.ica.2012.08.010

M3 - Article

AN - SCOPUS:84866696986

SN - 0020-1693

VL - 394

SP - 132

EP - 139

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene

Abstract

Keywords

ASJC Scopus subject areas

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