(2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

Yanko Moreno; Yimmy Salgado; María Teresa Garland; Ricardo Baggio

doi:10.1107/S0108270107046513

(2,2′-biquinoline-κ² N,N′)bis-(nitrato- κ² O,O′)copper(II)

Yanko Moreno, Yimmy Salgado, María Teresa Garland, Ricardo Baggio

Exact Sciences School

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu ^II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

Original language	English
Pages (from-to)	m487-m489
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	63
Issue number	11
DOIs	https://doi.org/10.1107/S0108270107046513
Publication status	Published - 13 Oct 2007

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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abstract = "In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.",

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T1 - (2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)

AU - Moreno, Yanko

AU - Salgado, Yimmy

AU - Garland, María Teresa

AU - Baggio, Ricardo

PY - 2007/10/13

Y1 - 2007/10/13

N2 - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

AB - In the title monomer, [Cu(NO3)2(C18H12N2)], the six-coordinated Cu II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

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DO - 10.1107/S0108270107046513

M3 - Article

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AN - SCOPUS:35948983004

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SP - m487-m489

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 11

ER -

(2,2′-biquinoline-κ² N,N′)bis-(nitrato- κ² O,O′)copper(II)

Abstract

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